New functionalities in abundant element oxides: ubiquitous
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Electrochimica Acta | Vol 218, Pages 1-356 (10 November
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a, Left is the crystal structure of C12A7 viewed from a 〈111〉 direction.A unit cell (lattice constant of 1.199 nm) with Z = 2 is indicated by a black frame. Right is the structure of a cage
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Fabrication of room temperature-stable 12CaO - SpringerLink
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Hiroshi Kageyama, 1 Katsuro Hayashi, 2 Kazuhiko Maeda, 3 J. Paul Attfield, 4 Zenji Hiroi, 5 James M. Rondinelli, 6 and Kenneth R The correlated anion disorder in AMON 2 perovskites is chemically symmetric through reversal of O and N. PDF analysis of neutron total scattering data for BaTaO 2 N reveals local O/N ordering originated from
CHEMISTRY OF HYDRIDE ION AND PROTON IN ANION
is known that there remains difficulty in con-trolling the crystal orientation (c-axis in the tetragonal structure) due to the particle size effect13 and the presence of OH groups in the shell region (surface and outer layer of crys-
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2011/01/01 · Translucent Ceramics of 12CaO · 7Al2O3 with Microporous Structure - Volume 17 Issue 6 - Katsuro Hayashi, Masahiro Hirano, Hideo Hosono. Available formats PDF Please select a format to send. By using this service, you agree that you will only keep articles for personal use, and will not openly distribute them via Dropbox, Google Drive or
Science and Technology of Advanced Materials: Vol 12, No 3
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Grain Orientation Dependence of the PTCR Effect in Niobium
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Current–Voltage Characteristics of Σ1 Boundaries with and
Katsuro Hayashi Hiroshi Yasuda Thermal field emission (TFE) from a flat surface of 12CaO∙7Al2O3 (C12A7) electride was examined at temperatures up to 900 °C and applied external voltages of 0
Stabilizationmechanismoftetragonalstructure
6) Katsuro Hayashi, Satoru Matsuishi, Toshio Kamiya, Masahiro Hirano, Hideo Hosono, Light-induced conversion of an insulating refractory oxide into a persistent electronic conductor, Nature (London) 419 (2002) 462. 7) Satoru Matsuishi, Yoshitake Toda, Masashi Miyakawa, Katsuro Hayashi, Toshio
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Light-induced conversion of an insulating refractory oxide
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(PDF) Fabrication of room temperature-stable 12CaO
Nickel nanoparticles were prepared by the arc discharge method. Argon and argon/hydrogen mixtures were used as plasma gas; the evaporation of anode material chiefly resulted in the formation of different arc-anode attachments at different hydrogen concentrations. The concentration of hydrogen was fixed at 0, 30, and 50 vol% in argon arc, corresponding to diffuse, multiple, and constricted arc
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George Hasegawa, Takaya Yano, Hirofumi Akamatsu, Katsuro Hayashi, Kazuki Nakanishi. Variation of meso- and macroporous morphologies in resorcinol–formaldehyde (RF) gels tailored via a sol–gel process combined with soft-templating and phase separation. Journal of Sol-Gel Science and Technology 2020, 965 DOI: 10.1007/s10971-020-05236-9.
Solid State Ionics | Vol 322, Pages 1-100 (September 2018
Nanomaterials 2018, 8, 684 3 of 12 Nanomaterials 2018, 8, x FOR PEER REVIEW 3 of 12 Figure 1. Schematic of the experimental setup for nickel nanoparticle production by direct current
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2003/08/01 · We removed ∼100% of clathrated oxygen ions from the crystallographic cages in a single crystal of 12CaO·7Al2O3, leading to the formation of high-density (∼2 × 1021 cm–3) electrons highly localized in the cages. The resulting electron forms a structure that we interpret as an F + center and migrates throughout the crystal by hopping to a neighboring cage with conductivity ∼100 siemens
Effect of Synthesis Time on Microscopic Characteristics of
2. Experimental. Figure 1 shows a schematic diagram of the experimental device used for preparing nickel nanoparticles and a synchronized high-speed camera for arc behavior observation. The setup is composed of a power source, an arc discharge chamber, a particle collector, and a gas circulator. Argon and/or hydrogen plasma gases were introduced to the system after the arc discharge chamber
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(PDF) Heavy doping of H− ion in 12CaO·7Al2O3
2004/12/20 · Katsuro Hayashi. Department of Materials Science, School of Engineering, The University of Tokyo, Tokyo 113‐8656, Japan. View the article PDF and any associated supplements and figures for a period of 48 hours. Article can not be printed. Article can not be downloaded.
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Room temperature-stable inorganic electride [Ca24Al28O68]4+4e- was employed for a pinacol coupling reaction in aqueous media. Ca−Al−O gel formed by the destruction of the crystal structure of an electride by water media played a key role in transferring the electron to electrophilic aldehydes. Aromatic aldehydes reacted smoothly with moderate to high yields.
Chloride-Ion-Stabilized Strontium Mayenite: Expansion of
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The effect of synthesis time on phase compositions, lattice constant and surface morphology of samples synthesized at 1773K were analyzed by XRD and SEM. The results are: the main phase of sample synthesized for 30min is 12CaO•7Al2O3, besides it also has little quantity of CaO•Al2O3. When prolonging synthesis time the phase tends to be 12CaO•7Al2O3 only.
Room Temperature-Stable Electride as a Synthetic Organic
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2007/03/28 · 12CaO · 7Al2O3 (C12A7) electride, which is synthesized by replacing free oxygen ions in cages with electron anions, has distinct advantages over electrides reported so far in respect of thermal and chemical stability and flexible preparation of various sample forms including single crystal, thin film, polycrystalline bulk and powder. These advantages, together with the fact that the
HQLWH Exploring Electro-active Functionality of
Reduction processes using metal hydride agents modify the chemical and structural properties of metal oxide crystals with different manners, depending on the host crystals and the process conditions [1]. In BaTiO3, a reduction using CaH2 leads to partial and random substitution of H-for the O2-site, which is compensated by a formal valence change of Ti4+ to Ti3+, imparting an electronic
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